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Fourth Ray Beauty After Hours

After Hours

Treat while you sleep! After Hours is formulated with Bamboo Charcoal, Salicylic Acid, Tea Tree, and Watermelon Seed, which work at night to absorb impurities and support skin clarity while a blend of oils nourish and balance moisture levels.
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Ingredient name what-it-does irr., com. ID-Rating
Vitis Vinifera (Grape) Seed Oil antioxidant, emollient com.:2-3 goodie
Caprylic/Capric Triglyceride emollient
Isononyl Isononanoate emollient
Citrullus Lanatus Seed Oil emollient
Melaleuca Alternifolia (Tea Tree) Leaf Oil soothing, anti-acne, antioxidant, antimicrobial/​antibacterial, perfuming goodie
Salicylic Acid exfoliant, anti-acne, soothing, preservative superstar
Cucumis Sativus (Cucumber) Seed Oil emollient goodie
Cucumis Sativus (Cucumber) Fruit Extract soothing, emollient goodie
Curcuma Longa (Tumeric) Root Oil perfuming
Charcoal Powder abrasive/​scrub
Tetrahexyldecyl Ascorbate antioxidant, skin brightening goodie
Oryza Sativa (Rice) Bran Extract
Helianthus Annuus (Sunflower) Extract soothing, emollient goodie
Prunus Amygdalus Dulcis (Sweet Almond) Seed Extract
Citrus Aurantium Amara (Bitter Orange) Flower Extract
Pyrus Malus (Apple) Fruit Extract moisturizer/​humectant goodie
Cucumis Melo (Melon) Fruit Extract
Cucumis Melo Cantalupensis Fruit Extract
Camellia Sinensis Leaf Extract antioxidant, soothing, antimicrobial/​antibacterial, emollient, moisturizer/​humectant superstar
Lavandula Angustifolia (Lanvender) Flower/Leaf/Stem Extract perfuming
Jasminum Officinale (Jasmine) Flower/Leaf Extract moisturizer/​humectant, perfuming, soothing
Rose Extract
Citrus Limon (Lemon) Peel Oil perfuming icky
Rosmarinus Officinalis (Rosemary) Leaf Extract antioxidant, soothing, antimicrobial/​antibacterial goodie
Citrus Aurantium Bergamia (Bergamot) Fruit Extract
Salvia Officinalis (Sage) Leaf Extract surfactant/​cleansing
Coffea Arabica (Coffee) Leaf/Seed Extract
Cupressus Sempervirens Leaf/Stem Extract
Cananga Odorata Flower Extract perfuming
Tourmaline Extract

Fourth Ray Beauty After Hours
Ingredients explained

Also-called: Grape Seed Oil | What-it-does: antioxidant, emollient | Comedogenicity: 2-3

A goodie plant oil coming from the polyphenol-rich seeds of the grape. It's a light emollient oil that makes your skin feel smooth and nice and also contains a bunch of good-for-the-skin stuff. It's a great source of antioxidant polyphenols, barrier repair fatty acid linoleic acid (about 55-77%, while oleic acid is about 12-27%) and antioxidant, skin-protectant vitamin E

What-it-does: emollient

A super common emollient that makes your skin feel nice and smooth. It comes from coconut oil and glycerin, it’s light-textured, clear, odorless and non-greasy. It’s a nice ingredient that just feels good on the skin, is super well tolerated by every skin type and easy to formulate with. No wonder it’s popular. 

What-it-does: emollient

An emollient ester with a rich and creamy but non-greasy skin feel. It makes skin supple and protects dry skin. 

Also-called: Watermelon Seed Oil | What-it-does: emollient

We don't have description for this ingredient yet.

Also-called: Tea Tree Oil, TTO | What-it-does: soothing, anti-acne, antioxidant, antimicrobial/antibacterial, perfuming

The famous tea tree oil. One of the best known essential oils which comes from Australia where it has been used for almost 100 years for its antiseptic and anti-inflammatory actions. Legend has it that the medicinal benefits of the oil were considered so important that Australian soldiers were supplied with some tea tree oil in their World War II military kit.

Similar to other essential oils, tea tree oil is a very complex chemical mixture consisting of about 100 components, the major ones being terpinen-4-ol (40%), γ-Terpinene (23%) and α-Terpinene (10%). Terpinen-4-ol is considered to be the main active component but as a great article in Clinical Microbiology Reviews states "while some TTO components may be considered less active, none can be considered inactive" and most components contribute to TTO's strong antibacterial, antiviral and antifungal effects

Expand to read more

Regarding skincare and tea tree oil, its most well-known effect is probably being a well established anti-acne ingredient. Multiple studies confirm that TTO is effective against the evil acne-causing bacteria called P. acnes and the effectiveness of 5% TTO gel is comparable to the gold standard anti-acne treatment, 5% Benzoyl Peroxide lotion. You need to be a bit more patient with TTO, though, as its effects come slower but also with fewer side effects.

Regarding TTO and sensitive skin, we say that you should be careful. Even if your skin is not sensitive you should never put undiluted TTO on your skin. Luckily, it contains only very small amounts of the common allergens (such as limonene), but irritant and allergic reactions still happen, especially by oxidation products that occur in older or not properly stored oil.  So if you have some pure TTO at home, know that storage matters, keep it in a cool, dry, dark place and use it up in a reasonable amount of time.

Overall, we do not often give a goodie status to essential oils, but we feel that TTO's unique antibacterial and anti-acne properties with its minimal allergen content warrant an exception. If your skin is acne-prone, TTO is something to experiment with.

Salicylic Acid - superstar
Also-called: BHA | What-it-does: exfoliant, anti-acne, soothing, preservative
  • It's one of the gold standard ingredients for treating problem skin
  • It can exfoliate skin both on the surface and in the pores
  • It's a potent anti-inflammatory agent
  • It's more effective for treating blackheads than acne
  • For acne combine it with antibacterial agents like benzoyl peroxide or azelaic acid
Read all the geeky details about Salicylic Acid here >>

Also-called: Cucumber Oil | What-it-does: emollient

When it comes to cucumber and skin care, cucumber fruit extract is the one that steals the show for its soothing and moisturizing properties. But cucumber also has seeds and these seeds contain oil that has nice fatty acids and emollient properties, similar to many other plant oils.

Cucumber oil is a high linoleic acid (60-69%) oil that also has a fair amount of oleic acid (9-20%). It also contains antioxidant vitamin E, phytosterols and some trace minerals such as potassium. It is a very light oil that is absorbed easily into the skin. It is described as an excellent oil for moisturization formulations.

Also-called: Cucumber Fruit Extract | What-it-does: soothing, emollient

Cucumber is a nice, non-irritating plant extract that’s known for it’s soothing and emollient properties. It’s not something new to put it on our face: even Cleopatra used it to “preserve her skin”.

It’s commonly believed that cucumber is the answer to puffy eyes, but there is no research confirming this. What research does confirm is that it contains amino acids and organic acids that’s helpful for the skin’s acid mantle. There is also an enzyme (called shikimate dehydrigenase) in the pulp that’s shown to have anti-inflammatory properties.

What-it-does: perfuming

We don't have description for this ingredient yet.

We don't have description for this ingredient yet.

Also-called: Form of Vitamin C, Ascorbyl Isotetrapalmitate, Ascorbyl Tetraisopalmitate, ATIP | What-it-does: antioxidant, skin brightening

Tetrahexyldecyl Ascorbate is a stable, oil-soluble form of skincare big shot Vitamin C. If you do not know, why Vitamin C is such a big deal in skincare, click here and read all about it. We are massive vitamin C fans and have written about it in excruciating detail.

So now, you know that Vitamin C is great and all, but it's really unstable and gives cosmetics companies many headaches. To solve this problem they came up with vitamin C derivatives, and one of them is Tetrahexyldecyl Ascorbate (let's call it ATIP in short).

Expand to read more

It's a really promising candidate (see below), but while reading all the goodness about it in a minute, do not forget that derivatives not only have to be absorbed into the skin but also have to be converted to pure vitamin C (ascorbic acid or AA) and the efficacy of the conversion is often unknown. In addition, vitamin C's three magic properties (antioxidant, collagen booster, skin brightener) are all properly proven in-vivo (on real people), but for the derivatives, it's mostly in-vitro studies or in the case of ATIP, it's in-vitro and done by an ingredient supplier.

With this context in mind let's see what ATIP might be able to do. First, it is stable (if pH < 5), easy to formulate and a joy to work with for a cosmetic chemist.

Second, because it's oil-soluble, its skin penetration abilities seem to be great. So great in fact, that it surpasses the penetration of pure vitamin C threefold at the same concentration and it penetrates successfully into the deeper layers of the skin (that is usually important to do some anti-aging work). There is also in-vitro data showing that it converts to AA in the skin. 

Third, ATIP seems to have all three magic abilities of pure vitamin C: it gives antioxidant protection from both UVB and UVA rays, it increases collagen synthesis (even more than AA) and it has a skin brightening effect by reducing melanogenesis by more than 80% in human melanoma cell cultures.

So this all sounds really great, but these are only in-vitro results at this point. We could find Tetrahexyldecyl Ascorbate mentioned only in one published in-vivo study that examined the anti-aging properties of a silicone formula containing 10% AA and 7% ATIP. The authors theorized that the 10% AA is released slowly from the silicon delivery system and probably stays in the upper layer of the skin to give antioxidant benefits, while ATIP penetrates more rapidly and deeply and gives some wrinkle-reducing benefits. The study was a small (10 patients), double-blind experiment, and the formula did show some measurable anti-aging results. However, it is hard to know how much pure vitamin C or ATIP can be thanked.

Bottom line: a really promising, but not well-proven vitamin C derivative that can be worth a try especially if you like experimenting (but if you like the tried and true, pure vitamin C will be your best bet).

We don't have description for this ingredient yet.

What-it-does: soothing, emollient

When it comes to sunflower and skincare, the seed oil is the common and well-known one. But according to manufacturer info, the seed extract also contains a bunch of skin goodies, including anti-inflammatory minerals, moisturizing and soothing amino acids, sugars and proteins as well as antioxidant polyphenol derivatives. 

We don't have description for this ingredient yet.

Also-called: Orange Flower Absolute

We don't have description for this ingredient yet.

Also-called: Apple Fruit Extract | What-it-does: moisturizer/humectant

Apple needs no introduction as one of the most common fruits on planet Earth. It's not only a healthy fruit snack, it's also a goodie if you put in all over your face. 

It's loaded with proteins, starch, sugars, acids, vitamins and salts. The sugars (mainly fructose, glucose, sucrose) give apple fruit extract nice moisturizing and smoothing properties, while the acids (mainly malic  and gallic acid) give it mild exfoliant, skin brightening and antibacterial properties. 

We don't have description for this ingredient yet.

What-it-does: astringent

We don't have description for this ingredient yet.

  • Green tea is one of the most researched natural ingredients
  • The active parts are called polyphenols, or more precisely catechins (EGCG being the most abundant and most active catechin)
  • There can be huge quality differences between green tea extracts. The good ones contain 50-90% catechins (and often make the product brown and give it a distinctive smell)
  • Green tea is proven to be a great antioxidant, UV protectant, anti-inflammatory, anticarcinogenic and antimicrobial
  • Because of these awesome properties green tea is a great choice for anti-aging and also for skin diseases including rosacea, acne and atopic dermatitis
Read all the geeky details about Camellia Sinensis Leaf Extract here >>

What-it-does: perfuming

We don't have description for this ingredient yet.

We don't have description for this ingredient yet.

We don't have description for this ingredient yet.

Also-called: Lemon Peel Oil | What-it-does: perfuming

The essential oil coming from the rind of the lemon that we make (or should make) lemonade from. In general, there are two problems with citrus peel oils: first, they are essentially the fragrant component, limonene in disguise (they are about 85-98% limonene).

Second, they contain the problematic compounds called furanocoumarins that make them mildly phototoxic. Lemon peel contains a medium amount of them, more than sweet orange but less than bergamot. Be careful with it especially if it is in a product for daytime use.  

Also-called: Rosemary Leaf Extract | What-it-does: antioxidant, soothing, antimicrobial/antibacterial

The extract coming from the lovely herb, rosemary. It contains lots of chemicals, including flavonoids, phenolic acids, and diterpenes. Its main active is rosmarinic acid, a potent antioxidant, and anti-inflammatory. It has also anti-bacterial, astringent and toning properties. 

The leaves contain a small amount of essential oil (1-2%) with fragrant components, so if you are allergic to fragrance, it might be better to avoid it. 

We don't have description for this ingredient yet.

Also-called: Sage Leaf Extract | What-it-does: surfactant/cleansing

We don't have description for this ingredient yet.

We don't have description for this ingredient yet.

We don't have description for this ingredient yet.

What-it-does: perfuming

We don't have description for this ingredient yet.

We don't have description for this ingredient yet.

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what‑it‑does antioxidant | emollient
com. 2-3
A goodie plant oil coming from the polyphenol-rich seeds of the grape. It's a light emollient oil that is a great source of antioxidant polyphenols, barrier repair fatty acid linoleic acid and antioxidant, skin-protectant vitamin E. 
what‑it‑does emollient
A very common emollient that makes your skin feel nice and smooth. Comes from coconut oil and glycerin, it’s light-textured, clear, odorless and non-greasy. [more]
what‑it‑does emollient
An emollient ester with a rich and creamy but non-greasy skin feel. [more]
what‑it‑does emollient
what‑it‑does soothing | anti-acne | antioxidant | antimicrobial/antibacterial | perfuming
The famous tea tree oil. One of the best known essential oils which comes from Australia where it has been used for almost 100 years for its antiseptic and anti-inflammatory actions. [more]
what‑it‑does exfoliant | anti-acne | soothing | preservative
One of the gold standard ingredients for treating problem skin. It can exfoliate skin both on the surface and in the pores (pH 3-4 needed) and it's a potent anti-inflammatory agent. [more]
what‑it‑does emollient
When it comes to cucumber and skin care, cucumber fruit extract is the one that steals the show for its soothing and moisturizing properties. But cucumber also has seeds and these seeds contain oil that has nice fatty acids and emollient properties, similar to many other plant oils.Cucumber oil is a high linoleic acid (60-69%) oil that also has a fair amount of oleic acid (9-20%). [more]
what‑it‑does soothing | emollient
Cucumber is a nice, non-irritating plant extract that’s known for it’s soothing and emollient properties. [more]
what‑it‑does perfuming
what‑it‑does abrasive/scrub
what‑it‑does antioxidant | skin brightening
A stable, oil-soluble form of Vitamin C, that might have (in-vitro results) all the magic abilities of pure vitamin C (antioxidant, collagen booster, skin brightener). [more]
what‑it‑does soothing | emollient
Sunflower seed extract that contains a bunch of skin goodies, including anti-inflammatory minerals, moisturizing and soothing amino acids, sugars and proteins as well as antioxidant polyphenol derivatives. [more]
what‑it‑does moisturizer/humectant
Apple fruit extract that's loaded with proteins, starch, sugars, acids, vitamins and salts. The sugars give apple nice moisturizing properties, while the acids give mild exfoliant, skin brightening and antibacterial properties.  [more]
what‑it‑does antioxidant | soothing | antimicrobial/antibacterial | emollient | moisturizer/humectant
Green Tea - one of the most researched natural ingredients that contains the superstar actives called catechins. It has proven antioxidant, anti-inflammatory, antimicrobial and anticarcinogenic properties. [more]
what‑it‑does perfuming
what‑it‑does moisturizer/humectant | perfuming | soothing
what‑it‑does perfuming
The essential oil coming from the rind of the lemon. Its main component (83-97%) is limonene, the super common fragrant ingredient. [more]
what‑it‑does antioxidant | soothing | antimicrobial/antibacterial
Rosemary leaf extract - Its main active is rosmarinic acid, a potent antioxidant, and anti-inflammatory. It has also anti-bacterial, astringent and toning properties. [more]
what‑it‑does surfactant/cleansing
what‑it‑does perfuming